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Asymmetric hydrogenation and transfer hydrogenation = edited by Virginie Ratovelomanana-Vidal, Phannarath Phansavath.

By: Contributor(s): Publisher: Hoboken, New Jersey : Wiley, [2021]Edition: First editionDescription: 384 paper معادلات ورسوم 24Content type:
  • text
Media type:
  • computer
Carrier type:
  • online resource
ISBN:
  • 9783527822300
  • 9783527346103
  • 9783527822317
  • 3527822313
Subject(s): Genre/Form: Additional physical formats: Print version:: Asymmetric hydrogenation and transfer hydrogenationDDC classification:
  • 547/.23 23
LOC classification:
  • QD281.H8
Online resources:
Contents:
7.3.1.2 Reduction Under Aqueous Conditions -- 7.3.1.3 Hydrogenation with Hydrogen Gas -- 7.3.1.4 Racemic Catalysts for Reductions -- 7.3.1.5 Specific Applications to Complex Acetophenone Derivatives -- 7.3.2 Reductions of Acetylenic Ketones -- 7.3.3 Reductions of Benzophenone Ketones -- 7.3.4 Reductions of Diverse Ketones -- 7.3.5 Dynamic Kinetic Resolutions -- 7.3.6 Reductions of Imines -- 7.4 Conclusions and Outlook -- References -- Chapter 8 Homogeneous Asymmetric Hydrogenation of Heteroaromatic Compounds Catalyzed by Transition Metal Complexes -- 8.1 Introduction -- 8.2 Asymmetric Hydrogenation of Quinolines -- 8.3 Asymmetric Hydrogenation of Quinoxalines -- 8.4 Asymmetric Hydrogenation of Isoquinolines -- 8.5 Asymmetric Hydrogenation of Pyridines and Pyrazines -- 8.6 Asymmetric Hydrogenation of Indoles and Pyrroles -- 8.7 Asymmetric Hydrogenation of Heteroarenes with Multi-N-Heterocycles -- 8.8 Asymmetric Hydrogenation of Other N-Heteroarenes -- 8.9 Asymmetric Hydrogenation of O- and S-Heteroarenes -- 8.10 Summary and Conclusions -- Acknowledgments -- References -- Chapter 9 Asymmetric (Transfer) Hydrogenation of Imines -- 9.1 Asymmetric Hydrogenation of Imines -- 9.1.1 Iridium Catalysts -- 9.1.1.1 (P,P) Ligands -- 9.1.1.2 (P,N) Ligands -- 9.1.1.3 P-Monodentate Ligands -- 9.1.2 Rhodium and Palladium Catalysts -- 9.2 Asymmetric Transfer Hydrogenation of Imines -- 9.2.1 Ruthenium Catalysts -- 9.2.2 Iridium and Rhodium Catalysts -- 9.2.3 Iron Catalysts -- 9.3 New Approaches -- 9.3.1 Metal Free -- 9.3.2 Biocatalytic Imine Reduction -- 9.3.2.1 Artificial Metalloenzymes -- 9.3.2.2 Imine Reductases (IREDs) -- 9.4 Summary and Conclusions -- References -- Chapter 10 Asymmetric Hydrogenation in Continuous-Flow Conditions -- 10.1 Introduction -- 10.2 Chirally Modified Metal Surfaces -- 10.3 Well-defined Transition-metal Complexes.
10.3.1 Immobilized Systems -- 10.3.1.1 Covalently Anchored Ligands -- 10.3.1.2 Immobilization by the Augustine Method -- 10.3.1.3 Ionic Liquids as Matrices for Transition-metal Complex Catalysts -- 10.3.2 Homogeneous Systems -- 10.3.3 Self-supported Systems -- 10.4 Organocatalysts -- 10.5 Chiral Auxiliary-controlled Asymmetric Hydrogenation in Flow -- 10.6 Summary and Outlook -- References -- Chapter 11 Organocatalytic Asymmetric Transfer Hydrogenation Reactions -- 11.1 Introduction -- 11.2 Reduction of C C Double Bonds -- 11.3 Reduction of C N Double Bonds -- 11.4 Cascade Reactions -- 11.5 Dearomatization -- 11.6 Conclusions -- References -- Index -- EULA.
Summary: "The development of efficient and straightforward methods to obtain chiral compounds is an important and challenging research area in modern synthetic organic chemistry. Especially asymmetric hydrogenation reactions have been investigated extensively in the past decades. This reaction methodology was pioneered by Knowles and Noyori (Nobel Prize in Chemistry 2001) and is now frequently used in both academia and industry. It is an economical reaction, easy to carry out, and environmentally friendly. It allows the efficient preparation of chiral building blocks of natural products, pharmaceuticals, agrochemicals, and flavors"--
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كتاب كتاب العلوم - حياة 661.1 R232 (Browse shelf(Opens below)) Available مكتبة قسم علوم الحياة 4971

Includes bibliographical references and index.

7.3.1.2 Reduction Under Aqueous Conditions -- 7.3.1.3 Hydrogenation with Hydrogen Gas -- 7.3.1.4 Racemic Catalysts for Reductions -- 7.3.1.5 Specific Applications to Complex Acetophenone Derivatives -- 7.3.2 Reductions of Acetylenic Ketones -- 7.3.3 Reductions of Benzophenone Ketones -- 7.3.4 Reductions of Diverse Ketones -- 7.3.5 Dynamic Kinetic Resolutions -- 7.3.6 Reductions of Imines -- 7.4 Conclusions and Outlook -- References -- Chapter 8 Homogeneous Asymmetric Hydrogenation of Heteroaromatic Compounds Catalyzed by Transition Metal Complexes -- 8.1 Introduction -- 8.2 Asymmetric Hydrogenation of Quinolines -- 8.3 Asymmetric Hydrogenation of Quinoxalines -- 8.4 Asymmetric Hydrogenation of Isoquinolines -- 8.5 Asymmetric Hydrogenation of Pyridines and Pyrazines -- 8.6 Asymmetric Hydrogenation of Indoles and Pyrroles -- 8.7 Asymmetric Hydrogenation of Heteroarenes with Multi-N-Heterocycles -- 8.8 Asymmetric Hydrogenation of Other N-Heteroarenes -- 8.9 Asymmetric Hydrogenation of O- and S-Heteroarenes -- 8.10 Summary and Conclusions -- Acknowledgments -- References -- Chapter 9 Asymmetric (Transfer) Hydrogenation of Imines -- 9.1 Asymmetric Hydrogenation of Imines -- 9.1.1 Iridium Catalysts -- 9.1.1.1 (P,P) Ligands -- 9.1.1.2 (P,N) Ligands -- 9.1.1.3 P-Monodentate Ligands -- 9.1.2 Rhodium and Palladium Catalysts -- 9.2 Asymmetric Transfer Hydrogenation of Imines -- 9.2.1 Ruthenium Catalysts -- 9.2.2 Iridium and Rhodium Catalysts -- 9.2.3 Iron Catalysts -- 9.3 New Approaches -- 9.3.1 Metal Free -- 9.3.2 Biocatalytic Imine Reduction -- 9.3.2.1 Artificial Metalloenzymes -- 9.3.2.2 Imine Reductases (IREDs) -- 9.4 Summary and Conclusions -- References -- Chapter 10 Asymmetric Hydrogenation in Continuous-Flow Conditions -- 10.1 Introduction -- 10.2 Chirally Modified Metal Surfaces -- 10.3 Well-defined Transition-metal Complexes.

10.3.1 Immobilized Systems -- 10.3.1.1 Covalently Anchored Ligands -- 10.3.1.2 Immobilization by the Augustine Method -- 10.3.1.3 Ionic Liquids as Matrices for Transition-metal Complex Catalysts -- 10.3.2 Homogeneous Systems -- 10.3.3 Self-supported Systems -- 10.4 Organocatalysts -- 10.5 Chiral Auxiliary-controlled Asymmetric Hydrogenation in Flow -- 10.6 Summary and Outlook -- References -- Chapter 11 Organocatalytic Asymmetric Transfer Hydrogenation Reactions -- 11.1 Introduction -- 11.2 Reduction of C C Double Bonds -- 11.3 Reduction of C N Double Bonds -- 11.4 Cascade Reactions -- 11.5 Dearomatization -- 11.6 Conclusions -- References -- Index -- EULA.

"The development of efficient and straightforward methods to obtain chiral compounds is an important and challenging research area in modern synthetic organic chemistry. Especially asymmetric hydrogenation reactions have been investigated extensively in the past decades. This reaction methodology was pioneered by Knowles and Noyori (Nobel Prize in Chemistry 2001) and is now frequently used in both academia and industry. It is an economical reaction, easy to carry out, and environmentally friendly. It allows the efficient preparation of chiral building blocks of natural products, pharmaceuticals, agrochemicals, and flavors"--

Description based on print version record and CIP data provided by publisher; resource not viewed.