Reaction kinetics and the development and operation of catalytic processes: proceedings of the 3rd international symposium, Oostende, Belgium, April 22 - 25, 2001/ Elektronische Ressource
edited by G. F. Froment; K. C. Waugh
- 1. ed
- Online-Ressource (xiii, 648 pages) : illustration ; 24 cm
- Studies in surface science and catalysis 133 .
Includes bibliographical references and index Chapter 28. Mass transfer through the gas-liquid interface at the presence of adsorbed active phospholipid monolayer.
Includes bibliographical references and index.
Front Cover; Reaction Kinetics and the Development and Operation of Catalytic Processes; Copyright Page; Contents; Introduction; PART 1: KEYNOTE LECTURES; Chapter 1. Adventures in catalytic nanospace: 'seeing' spillover in-situ for the first time; Chapter 2. From first-principles to catalytic turnovers: ethylene hydrogenation over palladium; Chapter 3. Development of microkinetic expressions by instationary methods; Chapter 4. Self sustained oscillations over copper in the catalytic oxidation of methanol; Chapter 5. Novel reactor configurations and modes of operation. Chapter 6. New methodologies and reactors for catalytic process developmentPART 2: KINETICS: STEADY STATE OPERATION; Chapter 7. Hysteresis kinetics of propene oxidation characterized by a Ag-Re supported membrane reactor; Chapter 8. Kinetics of oxidative dehydrogenation of LPG to olefins on Dy-Li-Cl-Zr-O catalyst; Chapter 9. De Donder relations and the theory of reaction routes; Chapter 10. A kinetic study of NO reduction by CO over a NiO/Al2O3 catalyst; Chapter 11. Reaction kinetics of the hydrodenitrogenation of methylcyclohexylamine over fluorinated NiMoS/Al2O3 catalysts. Chapter 12. Use of the ""dusty-gas"" model for the analysis of ethylbenzene oxidehydrogenation processChapter 13. Using low melting point alloy intrusion to quantify pore structure: Studies on an alumina catalyst support; PART 3: CATALYTIC PROCESSES; Chapter 14. Mass and heat transfer effects in the kinetic modelling of catalytic cracking; Chapter 15. Kinetics of ethylene polymerisation over CrY zeolites; Chapter 16. Investigations of the selective partial oxidation of methanol and the oxidative coupling of methane over copper catalysts. Chapter 17. A new kinetic model for hydrodesulfurization of oil productsChapter 18. Low-temperature, carbon-catalyzed, solvent-washed, trickle-bed sulfuric acid process; Chapter 19. Butane oxidation to maleic anhydride over a VPO catalyst following the riser regenerator approach; Chapter 20. Effects of particle size and modified SAPO-34 on conversion of methanol to light olefins and dimethyl ether; PART 4: MOLECULAR MODELING; Chapter 21. From DFT calculations to dynamic Monte Carlo simulations. The reactivity of CHx on the Ru(0001) surface; PART 5: REACTORS : NON STEADY STATE OPERATION. Chapter 22. Non-steady state operation of trickle-bed reactorsChapter 23. Performance enhancement of a microchannel reactor under periodic operation; Chapter 24. A dynamic study of steam-methane reforming; Chapter 25. Model-based optimization of the periodic operation of the Fischer-Tropsch synthesis; Chapter 26. Direct determination of periodic states of cyclically operated packed bed reactors; Chapter 27. Dynamics and control of a radial-flow ammonia synthesis reactor; PART 6: MISCELLANEOUS.
Reaction Kinetics and the Development and Operation of Catalytic Processesis a trendsetter. The Keynote Lectures have been authored by top scientists and cover a broad range of topics like fundamental aspects of surface chemistry, in particular dynamics and spillover, the modeling of reaction mechanisms, with special focus on the importance of transient experimentation and the application of kinetics in reactor design. Fundamental and applied kinetic studies are well represented. More than half of these deal with transient kinetics, a new trend made possible by recent sophisticated experimental equipment and the awareness that transient experimentation provides more information and insight into the microphenomena occurring on the catalyst surface than steady state techniques. The trend is not limited to purely kinetic studies since the great majority of the papers dealing with reactors also focus on transients and even deliberate transient operation. It is to be expected that this trend will continue and amplify as the community becomes more aware of the predictive potential of fundamental kinetics when combined with detailed realistic modeling of the reactor operation. Reaction Kinetics and the Development and Operation of Catalytic Processes is a trendsetter. The Keynote Lectures have been authored by top scientists and cover a broad range of topics like fundamental aspects of surface chemistry, in particular dynamics and spillover, the modeling of reaction mechanisms, with special focus on the importance of transient experimentation and the application of kinetics in reactor design. Fundamental and applied kinetic studies are well represented. More than half of these deal with transient kinetics, a new trend made possible by recent sophisticated experimental equipment and the awareness that transient experimentation provides more information and insight into the microphenomena occurring on the catalyst surface than steady state techniques. The trend is not limited to purely kinetic studies since the great majority of the papers dealing with reactors also focus on transients and even deliberate transient operation. It is to be expected that this trend will continue and amplify as the community becomes more aware of the predictive potential of fundamental kinetics when combined with detailed realistic modeling of the reactor operation